If you don't have the patience to slowly fill the void with spray foam through holes drilled in one of the studs, you could (if you were an experienced carpenter) use a Sawzall to remove one of the studs and re-frame the corner as a two-stud corner. Then you could either insulate the void with a fiberglass batt or simply present the two-stud corner to the spray-foam contractor as an accessible corner.
I recently did a remodel project for my basement using spray foam insulation. The original builder has used fiberglass, but I wanted the best insulation i could find. We chose closed cell foam because it blocks moisture from getting into the house. It took one day to install and was fumey for about 3 hours. It was pretty cool watching it being done. It comes out as a liquid and then expands rapidly into a foam. It's quick! Then they took a types of saw to shave it flat with the wall studs so we could then go ahead and drywall.

We are turning our roof into an unvented roof assembly by raising the roof and blowing in SPF. We are planning to leave the existing vapor barrier down but remove the fiberglass batting and then adding 6" of SPF in all the cavities, to completely seal and insulate the house. Should we have any concerns about doing it "upside down" and not spraying the foam directly to the underside/sheathing of the roof?
United Coatings™ Roof Coat Elastomeric Coating is an effective coating for providing long-term reflectivity over a wide range of roofing substrates. The high reflectivity of Roof Coat Elastomeric Coating keeps the roof substrate cool, which not only helps prolong its longevity but also helps save on energy costs. Roof Coat Elastomeric Coating’s rich consistency uniformly covers the textured profile of various substrates, forming a flexible monolithic membrane that provides protection from normal weathering, aging, and ultraviolet exposure. https://www.youtube.com/e/ggLAUsiuI_o

SPF application is fast and effective. Unlike traditional insulation types like fiberglass, which require a separate air-sealing step, spray foam can air seal and insulate a structure in one step, thus keeping the project moving forward. Combining these steps coupled with a spray-on application decreases installation time and delivers the ability to fit into hard-to-reach places, like eaves, odd-sized cavities, and rims. In addition to installation efficiencies, spray foam can provide excellent thermal, acoustical and indoor air quality performance in any climate. 
Carefully examine the roof membrane (surface material) for cracks, tears, blisters, evidence of ponding, exposed foam, and open seams. If already coated, evaluate the condition of the coating. Pay particular attention to areas around roof penetrations (vents, skylights, pipes, etc), ponding areas, cracks in parapet walls, and the attachment of roof membranes to parapet walls. Roofs should be in good condition to warrant coating.

Roof Bond

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