Heat which is created elsewhere that is transported by means of a fluid, such as water or in our case air. Spray foam insulation's most important attribute is the ability to air seal creating a custom airtight envelope within the building structure. The added benefit to air sealing is the ability to block convective heat transfer from interior to exterior during heating months and vice versa during cooling months, as the heat cannot escape through gaps in the buildings envelope without the aid of air movement from infiltration as a means of transport. https://www.youtube.com/v/ggLAUsiuI_o&feature=kp
If you're chemically sensitive, it's probably not a good idea to get it installed, but it's also not a good idea to breathe musty air from the crawl space either. In addition, your house and its contents are made of lots of materials that affect your indoor air quality. If you're really concerned about this, hire a company to test your air and tell you what you can do about it.
How Much Does Spray Foam
A. You can use closed-cell spray foam that way if you want, although you should realize that the spray foam will prevent the roof sheathing from drying inward. This approach should only be used if the roof sheathing is bone dry, because it will never dry when sandwiched in this manner. Most building scientists would prefer to see fiberglass rather than closed-cell spray foam under the roof sheathing in this type of assembly.
Jennifer, I'm not an expert on the health effects of closed cell foam. A lot of people live in houses with closed cell foam and have no health problems from it, at least not short-term, acute problems. I do know of one person who had it removed from her crawl space because she was convinced it caused her dog to get sick, but I know only what she told me.
SPF application is fast and effective. Unlike traditional insulation types like fiberglass, which require a separate air-sealing step, spray foam can air seal and insulate a structure in one step, thus keeping the project moving forward. Combining these steps coupled with a spray-on application decreases installation time and delivers the ability to fit into hard-to-reach places, like eaves, odd-sized cavities, and rims. In addition to installation efficiencies, spray foam can provide excellent thermal, acoustical and indoor air quality performance in any climate.