If you don't have the patience to slowly fill the void with spray foam through holes drilled in one of the studs, you could (if you were an experienced carpenter) use a Sawzall to remove one of the studs and re-frame the corner as a two-stud corner. Then you could either insulate the void with a fiberglass batt or simply present the two-stud corner to the spray-foam contractor as an accessible corner. http://www.youtube.com/e/ggLAUsiuI_o
The guys who sprayed my attic were trained and certified, but I later found out, too late, that they had no experience and my attic was the first they'd ever sprayed. I was also never told to vacate my house for any length of time, and so I (and my pets) were in the house the day they sprayed and the entire time the off ratio foam was filling my home with horrendous vapors. The company kept telling me that it was a good job and I had nothing to worry about, even after I'd had 2 other experienced sprayers from 2 different companies visually examine the foam and confirm that large areas appeared to be off ratio. The 3rd sprayer from yet another company, was also outraged because the company who did my attic had failed to vacuum up all of the old cellulose insulation, and he also noticed areas where the foam was shrinking or pulling away, and this was not even 5 weeks after the spraying.
I am an Architect in Toronto. I am designing a new roof addition to a row house building. Because of existing conditions and the shape of the new roof. It may be easiest to use closed cell spray foam within the areas of the joists. My question is when spray foam is used in this situation do I need to worry about how the joist members may be thermal bridges? It is not common to provide a little bit of rigid insulation to protect the joist members? The additional layer of outboard insulation will require an extra layer of plywood above the insulation which will add to cost.