Allison--would be very interested in your take on the GHG issues of foams, which have received lots of smart commentary recently. To highlight a few: architect Jesse Thompson's comments on Tom's Good vs Bad post on Energy Circle, the very thorough piece by Alex Wilson on Green Building Advisor and Michael Anschel's cautionary diatribe on Remodeling. 

Where Can You Buy Foam Spray

Global warming potential (GWP), as defined by the EPA, is a measure of how much energy the emissions of 1 ton of a gas will absorb over a given period of time, relative to the emissions of 1 ton of carbon dioxide (CO2).  Spray foam insulation products that use water as the blowing agent - typically open-cell foam however Icynene’s ProSeal Eco is a 100 percent water blown closed-cell spray foam – have a global warming potential of 1, the lowest possible number.  This is because water in the mixture reacts during the application process to release carbon dioxide and heat. The GWP of the blowing agent is that of carbon dioxide. Carbon dioxide has a GWP of 1.
Carefully examine the roof membrane (surface material) for cracks, tears, blisters, evidence of ponding, exposed foam, and open seams. If already coated, evaluate the condition of the coating. Pay particular attention to areas around roof penetrations (vents, skylights, pipes, etc), ponding areas, cracks in parapet walls, and the attachment of roof membranes to parapet walls. Roofs should be in good condition to warrant coating.

Roof Bond