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I used this for the rim-joist in our home. A couple things: I put 1in solid core foam (cut to size) in each bay before using the spray foam. I also was able to do a relatively 'thick' spray to close off any potential gaps that may have existed. I turned off the HVAC and turned on some fans in the windows to exhaust out the fumes, and wore a mask (3m respirator). http://www.youtube.com/watch?v=ggLAUsiuI_o&feature=youtube_gdata
I am an Architect in Toronto. I am designing a new roof addition to a row house building. Because of existing conditions and the shape of the new roof. It may be easiest to use closed cell spray foam within the areas of the joists. My question is when spray foam is used in this situation do I need to worry about how the joist members may be thermal bridges? It is not common to provide a little bit of rigid insulation to protect the joist members? The additional layer of outboard insulation will require an extra layer of plywood above the insulation which will add to cost.