You probably have some familiarity with spray foam insulation, and you may have even used the foam that comes in pressured spray cans at home improvement retailers. This foam is know as one-part foam, meaning that it is one continuous mixture that is simply applied to the area in need. One-part foam is frequently used for sealing small gaps and cracks.
You've got no argument from me there, Dennis. Getting a good installer if you're going with spray foam is crucial. Many builders or homeowners don't know how to find one, however, and that's where third party inspections come in. Also, even good installers have bad days, but if someone comes in behind them with a measuring probe and a Blower Door, there will be fewer sub-par foam jobs.  
I have used the Froth-Pak 200 to air-seal rim joists--the area above the foundation wall in a basement. The first time I used it I did not shake the canisters well enough and the foam did not cure properly. Don't just shake the box for a few seconds. I take the tanks out of the box so I can shake/invert each tank for a minute or two. You will be able to hear the chemical sloshing around in the tanks. Also, don't ignore the recommended temperature for application--around 75 degrees F.
Polyurethane is a closed-cell foam insulation material that initially contains a low-conductivity gas in its cells.[5] As a result of the high thermal resistance of the gas, spray polyurethane insulation typically has an initial R-value around R-3.4 to R-6.7 per inch.[5] In comparison, blown fiberglass typically has an R-Value of only R-3 to R-4 per inch.[6]
Seal It insulation is the first spray foam insulation company in the state of Maine, and it’s a worthy cause; one that we do not take lightly. Energy costs have, and will continue to, rise at a rate disproportionate to most family incomes. Many people wonder how they will be able to afford the upcoming cold weather; this is what we all face; and this is what we cannot ignore.

In general, cantilevered steel beams are a nightmare. If part of the steel beam is in contact with exterior temperatures, then it's best if the interior portion of the steel beam is covered on all sides with insulation. This is generally impossible (because the interior portion of the cantilevered beam generally supports a load, meaning that you can't wrap the steel beam in insulation on all sides).
There is a significant price difference when it comes to using foam insulation to insulate a new versus older home. Spraying insulation inside a newly constructed home is easier because the installation company can ensure the insulation will work effectively and design it for optimum defense against sound, heat transfer and utility costs. Installing spray foam in older homes that contain existing insulation can cost additional time and money -- it is not usually recommended as compared to weatherization or an energy aduit.
OK, Peter, I finally went back and read Alex Wilson's article on what he perceives as a serious problem. I haven't seen the full report, but based on the summary he wrote on the Green Building Advisor website, I question the science. It seems to me that he's chosen the wrong metric and he's basing his conclusion on too many assumptions because he doesn't have enough data. You can see my comments at the end of his article.
I have never used foam insulation before and this was easy for me to use right out of the box. I had a 4'x8"x8" cavity in my basement that houses a waterline. When the previous homeowner installed this they put no insulation in at all and being that it's an exterior wall in the basement and I live in the Midwest that thing was pushing so much cold air in it was incredibly uncomfortable. Out of the box and job completed in about 5 minutes. Stopped all drafts and created a nice 2" barrier on the wall in which I will install some extra bat insulation over it. 4 stars because the spray isn't very good passed 6-8" from the surface. Make sure you can reach the surface you want to coat. Great for small jobs!
Acrylic coatings are typically applied in two coats, with the second running perpendicular to the first. 1 gallon per 100 square feet is a good estimate for these coatings, as they do not need to be applied nearly as thick as many other coatings. These coatings can be sprayed or roll-applied. Acrylic coatings generally require a re-coat within 2-3 years of application.
As this example illustrates, it's important to seal the envelope completely. One of spray foam's biggest selling points is its air-sealing ability, but it can't seal places where it's not sprayed. One of the nice things about using spray foam in new construction is that you can do a Blower Door test before the drywall goes in. Even better, you can test for leaks with a fog machine.
Spray foam insulation, when properly installed is both an air barrier and when closed cell foam is used at the proper depth a vapor barrier!  Before hiring any contractor you should establish the brand of foam being used and verify that with the named manufacture.  Please ask for ESR reports and MSDS sheets on any foam being installed in your home. A couple areas where you might consider spray foam insulation include:

Check with the coating manufacturer who may be able to suggest applicators who have used their products and have familiarity with the application. Another option would be to interview contractors and ask specific questions about their proven ability to install roof coatings. Contractors affiliated with the National Roofing Contractors Association (NRCA) or local roofing contractor trade associations typically are more knowledgeable. Consult those groups’ websites for contractors.

Spray Foam Contractors

Open cell spray foam consists of cells that do not completely seal themselves. This makes for a softer and less dense final product. Closed cell foam cells are completely sealed and closed compressed together, creating a denser and firmer final product. This also gives closed cell foam a higher R-value (measured unit of thermal resistance). These differences also affect the cost difference between the two types of insulation.

How Much For Spray Foam Roof

FROTH-PAK Foam Sealant is a two-component quick-cure polyurethane FROTH-PAK Foam Sealant is a two-component quick-cure polyurethane foam that fills cavities penetrations cracks and expansion joints. FROTH-PAK foam sealant can also be used as a sealant and void fill in many roofing applications. FROTH-PAK is chemically cured foam which significantly reduces curing time. FROTH-PAK dispenses expands and becomes tack ...  More + Product Details Close
I don't even want to ask this question but... several years ago we hired a local contractor to spray high density foam on the roof deck and walls of our unfinished 2nd floor. We realized that the job was done poorly and cut an access into the attic space to assess things. We realize now that they spray foamed directly to the chimney (no flashing). The chimney is currently used for a woodstove and DHW venting. The DHW will go away but wood stove will remain. My question is, how bad (unsafe) is this? I have found information on foam exposure to fire but have not been able to find anything about temperature ratings in general (i.e. what happens on prolonged exposure to high temperatures).
The problem was that the installer was doing his first spray foam job ever, and the thickness of the insulation varied from zero (visible roof deck) to about 9". Unfortunately, good average thickness doesn't cut it. The coverage needs to be uniform because a lot of heat will go through the under-insulated areas. (See my article on flat or lumpy insulation performance.)
Roof coatings are easy to install. Smaller roofs in good, serviceable condition can be a weekend do-it-yourself (DIY) project. Larger roofs with leaks and ponding water issues should be coated by a qualified professional. Additional roof coating products, such as foam or coatings designed for seams, may be required underneath the main coating layers. Supplement coating products are used to reinforce damaged or leak-prone problem areas.[3]
This tropic heat actually is the cause that the steel structure, which most roofs in that part of the world are built on, expands and contracts all the time. By doing so, the sun-battered steel structure causes the roof tiles to dislodge and slowly creates small openings between the roof tiles, through which rain water can run into, creating leaks that can cause much damage to plastered ceilings and electric wiring.

Where To Purchase Spray Foam