Spray foam is a fully adhered insulation that is spray applied into wall cavities, providing a continuous air and moisture barrier. Spray foam allows efficient use of your HVAC system and helps regulate the temperature fluctuations and humidity in your home. Spray foam effectively seals the building envelope, filling in any cracks and crevices, the common source of air and moisture infiltration as well as temperature variations. http://kvsprayfoam.com/images/closed-cell-wall.jpg
Determining which type of SPF is right for the project involves evaluating the application area, overall budget, and scope of a project. Review insulation needs in attics, walls, ceilings, and other areas, and account for factors like project location, climate and how the building will be used. For example, an indoor swimming pool will drive towards a different SPF selection than an office building. 
Allison--would be very interested in your take on the GHG issues of foams, which have received lots of smart commentary recently. To highlight a few: architect Jesse Thompson's comments on Tom's Good vs Bad post on Energy Circle, the very thorough piece by Alex Wilson on Green Building Advisor and Michael Anschel's cautionary diatribe on Remodeling. 
Carefully examine the roof membrane (surface material) for cracks, tears, blisters, evidence of ponding, exposed foam, and open seams. If already coated, evaluate the condition of the coating. Pay particular attention to areas around roof penetrations (vents, skylights, pipes, etc), ponding areas, cracks in parapet walls, and the attachment of roof membranes to parapet walls. Roofs should be in good condition to warrant coating.

Roof Bond