Part of that guidance will be explaining that interior, two component foam is applied with the professional using specific personal protective equipment (high-pressure foam is installed while using a respirator, for example). It is encouraged that professionals explain clearly to customers that this equipment, coupled with certain work and engineering practices, including ventilation, is used to minimize exposures to the chemicals used to make SPF during the job.
A. You can use closed-cell spray foam that way if you want, although you should realize that the spray foam will prevent the roof sheathing from drying inward. This approach should only be used if the roof sheathing is bone dry, because it will never dry when sandwiched in this manner. Most building scientists would prefer to see fiberglass rather than closed-cell spray foam under the roof sheathing in this type of assembly.

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Steve: If your spray foam installer leaves the vents open, he will be committing the 2nd of the 4 problems I described above. You will most likely have comfort and efficiency problems. You may well have condensation problems. You will be spending a lot of money on a product that likely won't perform as it should. Don't let him leave the vents open. If the installer you've chosen doesn't understand this, you may want to choose someone else. 

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I don't know if it's common or uncommon, but installing a layer of rigid foam above your roof sheathing in order to interrupt thermal bridging is always a good idea, and is preferable in all respects to a roof assembly without any rigid foam above the sheathing. If you decide to install rigid foam above the roof sheathing, you shouldn't use closed-cell spray foam under the sheathing; either use open-cell spray foam (which is vapor-permeable) or a fluffy insulation like cellulose, mineral wool, or fiberglass (any of which will allow the roof sheathing to dry to the interior).

Spray foam’s thermal performance and advanced air and moisture control can be optimized by combining it with other insulation products like fiberglass batts or rolls, maximizing budget and meeting energy efficiency goals. Combining insulation products creates a custom solution by leveraging the functions of multiple materials to find the best mix for the project. 
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